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- Which of the following anions is the most nucleophilic in polar protic solvents? a. F- b. Cl- C. Br- d. I- O a. fluoride b. chloride O c. bromide O d. iodideWhich species is likely to undergo a reaction with the nucleophile readily? A. (ch3)3cl b. (Ch3)2HCI c. Ch3ch2cl d. CH3CIA -if the indicated property/behavior in item I is greater than in item II B-if the indicated property/behavior in item I is less than in item II. C- if the indicated property/behavior is equal in item I and item II. D- if the indicated data is insufficient to make a comparison.
- Which of the following parameters affects the rate and kinetics of a reaction? A. Solvent medium B. Reaction temperature C. Reaction time D. Geometry and structure of the alkyl halide E. pH1. Which of the following cannot be a nucleophile? a. Ib. IIc. III2. Which of the following cannot be an electrophile? a. Ib. IIc. IVWhat product is formed when 1-bromopropane reacts with each of the following nucleophiles? a. HO- b. -NH2 c. CH3S- d. HSf- e. CH3O- f. CH3NH2
- Which of the following molecules would react most rapidly in a nucleophilic substiution reaction? a. 2-lodo-2-methylpropane O b. 2-Bromo-2-methylpropane c. 2-Chloro-2-methylpropane O d. They would all react at the same rateBenzyl chloride is reacted with different nucleophiles (HO-, CH3COO-, PhO-, CH3O-). Arrange them in the decreasing order of reactivity with benzyl chloride. A. CH3O¯> HO- > PhO-> CH3CO0- B. HO->CH3O-> PhO> CH3CO0- C. HO-> PhO- > CH3O¯> CH3C- D. CH3COO-> CH³O¯> HO-> PhO- Note: benzyl chloride PhO, phenoxideCan you match best nucleophile / conditions that will give a successful hydrolysis reaction for each electrophile? 1. Acid chloride 2. Acetic anhydride 3. Ester 4. Amide a. LiAlH4; hydronium work-up b. PCC c. NaH d. CrO3 e. HOEt f. H3O+ or OH- g. H2O h. NaBH4;hydronium work-up
- Melphalan, a drug used in chemotherapy, reacts with itself in the body before binding with its target, as illustrated in the mechanism below. What is the first pattern of arrow pushing seen in this reaction? (Look at the first arrow coming from the Nitrogen with a lone pair). a. rearrangementc. nucleophilic attackFor Nos. 63-70 Choose: A -if the indicated property/behavior in item I is greater than in item II B-if the indicated property/behavior in item I is less than in item II. C- if the indicated property/behavior is equal in item I and item II. D- if the indicated data is insufficient to make a comparison. 63. Reactivity toward Nucleophilic Addition Reaction I. FCH₂CHO II. CH3CHOA -if the indicated property/behavior in item I is greater than in item II B-if the indicated property/behavior in item I is less than in item II. C- if the indicated property/behavior is equal in item I and item II. D- if the indicated data is insufficient to make a comparison.