2.48 The molar heat capacity of for temperatures in the range 300 to erate pressures can be approximate a = 6.15 cal mol- K-l and b = (a) Calculate q, w, AU, and AH v versibly heated from 27°C to 12 1.00 atm. Assume perfect-gas behav and AH when 2.00 mol of O, initia. heated from 27°C to 127°C with V

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter2: The First Law Of Thermodynamics
Section: Chapter Questions
Problem 2.12E: If the heat capacity varies withtemperature, abetter form ofequation 2.9 isto solve q=TiTfnCT-t A...
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2.48 The molar heat capacity of oxygen at constant pressure
for temperatures in the range 300 to 400 K and for low or mod-
erate pressures can be approximated as Cpm
a = 6.15 cal mol- K- and b
(a) Calculate q, w, AU, and AH when 2.00 mol of 0, is re-
versibly heated from 27°C to 127°C with P held fixed at
1.00 atm. Assume perfect-gas behavior. (b) Calculate q, w, AU,
and AH when 2.00 mol of O, initially at 1.00 atm is reversibly
heated from 27°C to 127°C with V held fixed.
= a + bT, where
0.00310 cal mol- K-2.
%3D
Transcribed Image Text:2.48 The molar heat capacity of oxygen at constant pressure for temperatures in the range 300 to 400 K and for low or mod- erate pressures can be approximated as Cpm a = 6.15 cal mol- K- and b (a) Calculate q, w, AU, and AH when 2.00 mol of 0, is re- versibly heated from 27°C to 127°C with P held fixed at 1.00 atm. Assume perfect-gas behavior. (b) Calculate q, w, AU, and AH when 2.00 mol of O, initially at 1.00 atm is reversibly heated from 27°C to 127°C with V held fixed. = a + bT, where 0.00310 cal mol- K-2. %3D
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