2. Which of the following compounds exhibit cis/trans isomerism? Explain why. Draw the Cis and trans forms of the compounds that do exhibit isomerism. a) Methylcyclobutane b) 3-ethyl-3-hexene c) 1-ethyl-3-methylcyclopentane la noeneolsleb d) 2,3-dimethylpentane (oirs S) dw enylud-t-lyrtom Eto nolterogal b e) 2,3-dichloro-2-hexene onstudoipttsnib-Eto f) 2-butyne
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- 2. Which of the following compounds could have configurational isomerism (cis or trans) and if they do, draw the both of the structures and label them as cis and trans d) 1,2-dichloroethene e) 2-methyl-2-butene f) 1-chloropropeneName the following molecule. CH₂CH3 H-CH3 H3C H Br (2R, 3R)-2-bromo-3-methylpentane (2S,3S)-2-bromo-3-methylpentane O (2R,3S)-2-bromo-3-methylpentane (1R, 2S)-1-bromo-1,2-dimethylbutane (1S,2R)-1-bromo-1,2-dimethylbutane2) The condensed structure of 2,4-dimethylheptane is Hас— сн—сн-сн—сH2-сH2-СH; ČH3 CHз СНЗСНЗСН2СНЗСН2СH2СHЗ CH-CH-CH2-CH3 I I. CH, CHз Нас- Hас— сн—сн2—сн-сн,—сн—СH—CHз CHз ČH3 CH3 HG -CH2- H3C- -CH--CH2-CHз CHз H3C
- 1 12. Identify the set of compounds that have the same functional group. (a) C2H6, C2H4, C2H2 (b) C2H2, CH3COOH, CH3CONH2 (с) СНЗСН2CНО, Н2СО, СНЗСH2CH2CH2CНO (d) CH3NH2, CH3CH2CONH2, CH3CH2CONHCH3 (e) СНЗС(О)СНз, СНЗСООН, CH:CH2CHOA.) On any clean sheet of paper, draw both the condensed and line-bond structure of the following compounds: 1) 3-ethylhexane 2) 1,3-dimethylcyclopentane 3) 1,3-dichloro-3-methylheptane ( Cl- , Chloro branch) 4) bromocyclobutane (Br-, Bromo branch) 5) 5-sec-butylnonane 6) 4-t-butylheptane 7) 4-ethylcycloheptene 8) 4,4-dimethylpent-2-ene 9) 3-chloro-2,7-dimethylnon-4-yne (Cl- Chloro branch) 10) 1-cyclohexylbut-2-yneb) Draw the structures (use line angle formula or Lewis structure) for the following compounds. Don't use common names such as isopropyl. tertiary butyl. i) 2-bromo-3-(1', 1'-dimethylethyl)-5-chlorohexane ii) 1-bromo-3-(1'-methylethyl)-5-methylhexane iii) Draw cis and trans isomers for 2,3-dimethyl-3-hexene.
- 1) Complete the table to show whether the alkenes exhibit E-Z isomerism. 2) Once finished, try and decide whether any E-Z isomers are E or Z isomers. E-Z Isomers? (/X) Name Structure Isomer 1 Isomer 2 methylpropene 1-chloropropene 2-ethylpent-1-ene 3-methylpent-2- ene 3,4-dimethyhex-3-ene 2-bromo-3 chlorobut-2-ene Fatty acids (26.5- Q3) Guidance on writing Q3 Why monounsaturated fatty acids have have E/Z isomerism Example of E isomer and how to differentiate to Z Isomer Health issues associated with Z (trans) isomer2. Draw structures for each of the following (a) cis-2,3-Dichloro-2-hexene (b) trans-2-burene © 1,3-dimethylcyclohexeneButanal (C4H&O) has eight H atoms. Suppose that any of these H atoms can be replaced by a Cl atom to yield a molecule with the formula C4H¬CIO. (a) Identify two H atoms where this substitution would yield constitutional isomers of C4H7CIO; (b) enantiomers of C4H;CIO; (c) conformers of C4H;CIO. H. H H H нн H Butanal O=U
- 1) Complete the table to show whether the alkenes exhibit E-Z isomerism. 2) Once finished, try and decide whether any E-Z isomers are E or Z isomers. E-Z Isomers? (/X) Name Structure Isomer 1 Isomer 2 methylpropene 1-chloropropene 2-ethylpent-1-ene 3-methylpent-2- ene 3,4-dimethyhex-3-ene 2-bromo-3 chlorobut-2-eneWhich of the following substances exist as can cis–trans isomers? Draw both isomers for those that do.(a) 2,3-Dimethylpent-2-ene (condensed structures only)(b) 2-Methylhex-2-ene (both condensed and line structures)(c) Hex-2-ene (line structures only)5a) Construct a model of butene, C4H8, using two carbon atoms with planar geometry and two carbon atoms with tetrahedral geometry. How many other isomers of C₂H, can you construct? Draw a dash structural representation of each structure. 5b) How many bonds in butene enjoy free rotation?