2. The following three experiments where run and initial rates of reaction were determined. 2 HgChaq) + C2O42-(a9) → 2 Cl-(aq) + 2 CO2«) +Hg2Cl26) Initial [HgCl2] (M) | [C2042-] (M) | Rate (M/s) 0.10 0.10 1.3 x 10-7 0.10 0.20 5.2 x 10-7 0.20 0.20 1.0 x 10-6 (a) Determine the reaction order for each reactant and write the rate law. (show some justification the chart or in words) (b) What is the overall order of the reaction? (c) Determine the value of k and report correct units. (d) Calculate the rate of the reaction when [C,0,²]= 0.040 M and [HgCl2] = 0.50 M.

Chemistry: An Atoms First Approach
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Author:Steven S. Zumdahl, Susan A. Zumdahl
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Chapter11: Chemical Kinetics
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Problem 5ALQ: Consider the following statements: In general, the rate of a chemical reaction increases a bit at...
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2. The following three experiments where run and initial rates of reaction were determined.
2 HgC2aq) + C204²-(aq) →2 Cl-(aq) +2 CO2«) +Hg2Cl26)
Initial
[HgCl2] (M) | [C2042-] (M) | Rate (M/s)
0.10
0.10
1.3 x 10-7
0.10
0.20
5.2 x 10-7
0.20
0.20
1.0 x 10-6
(a) Determine the reaction order for each reactant and write the rate law. (show some justification on
the chart or in words)
(b) What is the overall order of the reaction?
(c) Determine the value of k and report correct units.
(d) Calculate the rate of the reaction when [C,0,²]= 0.040 M and [HgCl,] = 0.50 M.
Transcribed Image Text:2. The following three experiments where run and initial rates of reaction were determined. 2 HgC2aq) + C204²-(aq) →2 Cl-(aq) +2 CO2«) +Hg2Cl26) Initial [HgCl2] (M) | [C2042-] (M) | Rate (M/s) 0.10 0.10 1.3 x 10-7 0.10 0.20 5.2 x 10-7 0.20 0.20 1.0 x 10-6 (a) Determine the reaction order for each reactant and write the rate law. (show some justification on the chart or in words) (b) What is the overall order of the reaction? (c) Determine the value of k and report correct units. (d) Calculate the rate of the reaction when [C,0,²]= 0.040 M and [HgCl,] = 0.50 M.
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