2. Nitric acid, which is among the top 15 chemicals produced in the United States, was first prepared over 1200 years ago by heating naturally occurring sodium nitrate (called saltpeter) with sulfuric acid and collecting the vapors produced. Calculate AH°rxn for this reaction. AH°f [NaNO3(s)] = -467.8 kJ/mol; AH°f [NaHSO4(s)]=-1125.5 kJ/mol; AHᵒf [H2SO4(1) = -814.0 kJ/mol; AH°f [HNO3(g)] = -135.1 kJ/mol NaNO3(s) + H2SO4(1)→ NaHSO4(s) + HNO3(g) [(-135.1) + (-1125.5)]-[(-814.0) + (-467.8)] -1260.6-(-1281.8) = 21.2 KS A)-644.2 kJ B) 644.2 kJ C) 21.2 KJ D) -21.2 kJ E)-291.4 kJ

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
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Chapter8: Thermochemistry
Section: Chapter Questions
Problem 11QAP: When one mol of KOH is neutralized by sulfuric acid, q=56 kJ. (This is called the heat of...
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B)-139.5 KJ
C) 104.4 kJ
D) 139.5 kJ
E) -104.4 kJ
[(-657,0) + 2(-241.8)]-[(923) + (-910.9)]
-1140.6 - (-1280.1) = 139.5 K)
F
2. Nitric acid, which is among the top 15 chemicals produced in the United States, was first prepared over 1200
years ago by heating naturally occurring sodium nitrate (called saltpeter) with sulfuric acid and collecting the
vapors produced.
poci
Calculate AH°rxn for this reaction. AH°f [NaNO3(s)] = -467.8 kJ/mol; AH°f [NaHSO4(s)] =-1125.5 kJ/mol;
AH°f [H2SO4(1) = −814.0 kJ/mol; AH°f [HNO3(g)] = -135.1 kJ/mol
A)-644.2 kJ
B) 644.2 kJ
C) 21.2 kJ
D) -21.2 kJ
E)-291.4 kJ
NaNO3(s) + H2SO4(1)→ NaHSO4(s) + HNO3(g)
[(-135.1) + (-1125.5)]-[(-814.0) + (-467.8)]
-1260-6-(-1281.8) = 21.2 k)
and the boiling water in the beaker. The temperature of the polling water is also the temperatur
hot metal.
10
TH
S
6
Transcribed Image Text:B)-139.5 KJ C) 104.4 kJ D) 139.5 kJ E) -104.4 kJ [(-657,0) + 2(-241.8)]-[(923) + (-910.9)] -1140.6 - (-1280.1) = 139.5 K) F 2. Nitric acid, which is among the top 15 chemicals produced in the United States, was first prepared over 1200 years ago by heating naturally occurring sodium nitrate (called saltpeter) with sulfuric acid and collecting the vapors produced. poci Calculate AH°rxn for this reaction. AH°f [NaNO3(s)] = -467.8 kJ/mol; AH°f [NaHSO4(s)] =-1125.5 kJ/mol; AH°f [H2SO4(1) = −814.0 kJ/mol; AH°f [HNO3(g)] = -135.1 kJ/mol A)-644.2 kJ B) 644.2 kJ C) 21.2 kJ D) -21.2 kJ E)-291.4 kJ NaNO3(s) + H2SO4(1)→ NaHSO4(s) + HNO3(g) [(-135.1) + (-1125.5)]-[(-814.0) + (-467.8)] -1260-6-(-1281.8) = 21.2 k) and the boiling water in the beaker. The temperature of the polling water is also the temperatur hot metal. 10 TH S 6
Expert Solution
Step 1

 

2. Recall the given reaction,                             NaNO3 s + H2SO4 l  NaHSO4 s + HNO3 gH°f NaNO3 s = - 467.8 KJmol ; H°f NaHSO4 s = - 1125.5 KJmolH°f H2SO4 l = - 814.0 KJmol ; H°f HNO3 g = - 135.1 KJmolWe have to calculate the H°rxn for the above reaction.

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