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- АСTIVITY 2 Directions: Determine the functional groups in the following molecules and provide short description in each item. 1. OH 2. нн нн H-C-C-0-Ç–C-H 3. нн нн H-Ņ-CH3 4. | CH3 5. H3C• -ċ-s- H- CH3 :Z-IThionyl choride, SOCl2, is a reagent commonly used to convert the –OH group of an alcohol to a better leaving group. What is the formal charge on S in this molecule? A) +2 B) +1 C) 0 D) -1 E) -2CH3 H3C. 1. ČH3 3-isopropyl-5-methylcyclohexanol There are four cis,trans isomers for 3-isopropyl-5-methylcyclohexanol, where the cis,trans designations of the substituents are made relative to the OH group: • up, up, up (cis,cis) • up, up, down (cis,trans) down (trans.cis) • up, down, • up, down, up (trans,trans) Consider the most stable chair for each of these isonmers, and then draw the most stable and least stable isomer based on a comparison of the best chair for each one. • To simplify matters, consider only axial vs equatorial energies of the groups (i.e. do not worry about the interactions between the groups, which in reality is also • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • You do not have to explicitly draw H atoms. • Use "flat" representations of rings, not chairs, in your drawing. Most stable Least stable
- The general formal for alkanes - 3 .compounds is A - CnH2n. O B - CnHn+2. O C - CnH2n+2. O General formula of aromatic - 4 .compounds are A - CnH2n. O B - CnHn+2. O C - CnH2n-2. ODraw an expanded structural formula of pent-1-en-3-yne/ CH3-CC-CH=CH2 and then label each carbon. Indicate the longest and shortest C-H bond and predict the C—C single bond that has the highest BDE(bond dissociation energy).NHČCH: CH,NH, NH2
- 9. Which of these structures are isomers? CH, — CH—CH, —СІ а) CH,–CH3 А. a and b CH; — CH—СH, — СH; b) В. а, b, and c CH,Cl С. а, с, and d с) CH3-CH-ÇHCICH3 D. b and c CH3 d) CH;-CH-CH,-CH–CH3 CH3 ČIWhich statement is incorrect about ?(butene (CH3-CH2-CH=CH2 Z)-But-2-ene is more stable than) O .(E)-but-2-ene Butene contains two sp2 hybridized O .C atoms Butene has two constitutional O .isomers Hydrogenation of butene gives O .butane4. What are the IUPAC names of the compound shown below? A) B) D) CH3 I O || CH3-CH-CH₂-C-OH سلہ "NH₂ CH3 1 CH3 CH2N-CH3 O || CH3-CH2-C-0-CH2-CH3
- Is 2-methyl-prop-1-ene symmetric? Please explain why with emphasis on the hybridization of each carbon in the C-C double bond.Draw the skeletal (line-bond) structure of [CH3CH2CHC(O)CH2CH2CH3]-. Include all lone pairs and charges as appropriate.Which is a correct resonance structure for compound A below: H2C=CH-C*H-CH=O (Compound A) 2. H2C=CH-CH=CH-O* 3. H2C=CH-c*H=CH-O I. H2C*-CH=CH-CH=O 4. H2C=C*H=CH-CH=DO O 3 and 4 O 2 and 3 O 1 and 4 01 and 2 MacBook A 20 F3 O00 F1 F2 F4 F5 F6 $ 2 6. Q W E Y S D F G T # 3