2. (a) The v(CO) of isoelectronic series [Mn(CO)], [Cr(CO)] and [V(CO) are 2090 cm³¹ 2000cm¹ and 1860 cm¹, respectively. Why is this difference observed in the band positions?

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
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2.
(a) The v(CO) of isoelectronic series [Mn(CO)], [Cr(CO)] and
[V(CO), are 2090 cm¹ 2000cm¹ and 1860 cm¹, respectively.
Why is this difference observed in the band positions?
Transcribed Image Text:2. (a) The v(CO) of isoelectronic series [Mn(CO)], [Cr(CO)] and [V(CO), are 2090 cm¹ 2000cm¹ and 1860 cm¹, respectively. Why is this difference observed in the band positions?
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