17. A first order decomposition reaction was found tohave an initial rate of 0.19 M-min- when the initialreactant concentration was 0.33 M. What is theinitial rate of reaction if the initial concentration isincreased to 0.45 M?D. 0.19 M·minE. 0.58 M·min-A. 0.26 M·min-B. 1.3 M-min¬1C. 0.78 M·min-

The rate law of the first-order reaction is given by The rate constant of the reaction is…

Answered: 17. A first order decomposition…

Chemistry: Matter and Change

1st Edition

ISBN:9780078746376

Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom

Publisher:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom

Chapter16: Reaction Rates

Section: Chapter Questions

Problem 76A

See similar textbooks

Similar questions

The reaction NO(g) + O,(g) — NO,(g) + 0(g) plays a role in the formation of nitrogen dioxide in automobile engines. Suppose that a series of experiments measured the rate of this reaction at 500 K and produced the following data; [NO] (mol L ’) [OJ (mol L 1) Rate = -A[NO]/Af (mol L_1 s-1) 0.002 0.005 8.0 X 10"'7 0.002 0.010 1.6 X 10-'6 0.006 0.005 2.4 X IO-'6 Derive a rate law for the reaction and determine the value of the rate constant.
Candle wax is a mixture of hydrocarbons. In the reaction of oxygen with candle w ax in Figure 11.2, the rate of consumption of oxygen decreased with time after the flask was covered, and eventually' the flame went out. From the perspective of the kinetic-molecular theory, describe what is happening in the flask. FIGURE 11.2 When a candle burns in a closed container, the flame will diminish and eventually go out. As the amount of oxygen present decreases, the rate of combustion will also decrease. Eventually, the rate of combustion is no longer sufficient to sustain the flame even though there is still some oxygen present in the vessel.
A reaction of the form aAProducts gives a plot of ln[A] versus time (in seconds), which is a straight line with a slope of 7.35 X 103. Assuming [A]0 = 0.0100 M, calculate the time (in seconds) required for the reaction to reach 22.9% completion.
For the reaction A + B C, explain at least two ways in which the rate law could be zero order in chemical A.
The hydrolysis of the sugar sucrose to the sugars glucose and fructose, C12H22O11+H2OC6H12O6+C6H12O6 follows a first-order rate equation for the disappearance of sucrose: Rate =k[C12H22O11] (The products of the reaction, glucose and fructose, have the same molecular formulas but differ in the arrangement of the atoms in their molecules.) (a) In neutral solution, k=2.11011s1 at 27 C and 8.51011s1 at 37 C. Determine the activation energy, the frequency factor, and the rate constant for this equation at 47 C (assuming the kinetics remain consistent with the Arrhenius equation at this temperature). (b) When a solution of sucrose with an initial concentration of 0.150 M reaches equilibrium, the concentration of sucrose is 1.65107M . How long will it take the solution to reach equilibrium at 27 C in the absence of a catalyst? Because the concentration of sucrose at equilibrium is so low, assume that the reaction is irreversible. (c) Why does assuming that the reaction is irreversible simplify the calculation in pan (b)?
The following data have been determined for the reaction: I+OCIIO+CI 1 2 3 [I] 0.10 0.20 0.30 [OCI] 0.050 0.050 0.010 Rate(mol/L/s) 3.05104 6.20104 1.83104 Determine the rate equation and the rate constant for this reaction.
Use the data provided in a graphical method to determine the order and rate constant of the following reaction: 2PQ+W Time (s) 9.0 13.0 18.0 22.0 25.0 [P] (M) 1.077103 1.068103 1.055103 1.046103 1.039103
The rate of the decomposition of hydrogen peroxide, H2O2, depends on the concentration of iodide ion present. The rate of decomposition was measured at constant temperature and pressure for various concentrations of H2O2and of KI. The data appear below. Determine the order of reaction for each substance, write the rate law, and evaluate the rate constant. Rate [H2OJ [Kll (mL min-’) (mol L ’) (mol L ’) 0.090 0.15 0.033 0.178 0.30 0.033 0.184 0.15 0.066
Consider a reaction of the type aA products, in which the rate law is found to he rate = k[A]3 (termolecular reactions are improbable but possible). If the first half-tife of the reaction is found to he 40. s, what is the time for the second half-life? Hint: Using your calculus knowledge, derive the integrated rate law from the differential rate law for a tennolecular reaction: Rate=d[A]dt=k[A]3
In the gas-phase reaction, I2+Cl22ICl,[I2] changesfrom 0.400M at 0.00 min to 0.300M at 4.00 min.Calculate the average reaction rate in moles of I2 consumedper liter per minute.

Recommended textbooks for you

Chemistry: Matter and Change

Chemistry

ISBN:

9780078746376

Author:

Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom

Publisher:

Glencoe/McGraw-Hill School Pub Co

Chemistry: The Molecular Science

Chemistry

ISBN:

9781285199047

Author:

John W. Moore, Conrad L. Stanitski

Publisher:

Cengage Learning

Chemistry for Engineering Students

Chemistry

ISBN:

9781337398909

Author:

Lawrence S. Brown, Tom Holme

Publisher:

Cengage Learning

Chemistry: Matter and Change

Chemistry

ISBN:

9780078746376

Author:

Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom

Publisher:

Glencoe/McGraw-Hill School Pub Co

Chemistry: The Molecular Science

Chemistry

ISBN:

9781285199047

Author:

John W. Moore, Conrad L. Stanitski

Publisher:

Cengage Learning

Chemistry for Engineering Students

Chemistry

ISBN:

9781337398909

Author:

Lawrence S. Brown, Tom Holme

Publisher:

Cengage Learning

Introduction to General, Organic and Biochemistry

Chemistry

ISBN:

9781285869759

Author:

Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres

Publisher:

Cengage Learning

Chemistry by OpenStax (2015-05-04)

Chemistry

ISBN:

9781938168390

Author:

Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser

Publisher:

OpenStax

Chemistry

ISBN:

9781305957404

Author:

Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:

Cengage Learning

SEE MORE TEXTBOOKS