(13) Calculate the freezing point of a solution containing 5.0 grams of KCl and 550.0 grams ofwater. The molal-freezing-point-depression constant (Kf) for water is 1.86°C/m.A) -0.45 OCB) +0.45 °CC) -0.23 OCD) +0.23 °CE) 1.23 oC

Kf for water = 1.86°C/m For KCl, van’t Hoff factor, i = 2 Normal freezing point of water, T1 =…

Answered: (13) Calculate the freezing point of a…

General, Organic, and Biological Chemistry

7th Edition

ISBN:9781285853918

Author:H. Stephen Stoker

Publisher:H. Stephen Stoker

Chapter8: Solutions

Section: Chapter Questions

Problem 8.93EP: What would be the freezing point of a solution formed by adding 1.0 mole of glucose (a molecular...

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The vapor pressures of several solutions of water-propanol (CH3CH2CH2OH) were determined at various compositions, with the following data collected at 45C: H2O Vapor pressure(torr) 0 74.0 0.15 77.3 0.37 80.2 0.54 81.6 0.69 80.6 0.83 78.2 1.00 71.9 a. Are solutions of water and propanol ideal? Explain. b. Predict the sign of Hsoln for water-propanol solutions. c. Are the interactive forces between propanol and water molecules weaker than, stronger than, or equal to the interactive forces between the pure substances? Explain. d. Which of the solutions in the data would have the lowest normal boiling point?
A solution is made by dissolving 34.0 g of NaCl in 100 g of H2O at 0C. Based on the data in Table 8-1, should this solution be characterized as a. saturated or unsaturated b. dilute or concentrated
What would be the freezing point of a solution formed by adding 1.0 mole of glucose (a molecular compound) to the following amounts of water? a. 250 g (0.25 kg) b. 500 g (0.500 kg) c. 1000 g (1.000 kg) d. 2000 g (2.000 kg)
A 1.00 mol/kg aqueous sulfuric acid solution, H2SO4,freezes at 4.04 C. Calculate i, the vant Hoff factor,for sulfuric acid in this solution.
The freezing-point depression of a 0.091-m solution of CsCl is 0.320C. The freezing-point depression of a 0.091-m solution of CaCl2 is 0.440C. In which solution does ion association appear to be greater? Explain.
6-111 As noted in Section 6-8C, the amount of external pressure that must be applied to a more concentrated solution to stop the passage of solvent molecules across a semipermeable membrane is known as the osmotic pressure The osmotic pressure obeys a law similar in form to the ideal gas law (discussed in Section 5-4), where Substituting for pressure and solving for osmotic pressures gives the following equation: RT MRT, where M is the concentration or molarity of the solution. (a) Determine the osmotic pressure at 25°C of a 0.0020 M sucrose (C12H22O11) solution. (b) Seawater contains 3.4 g of salts for every liter of solution. Assuming the solute consists entirely of NaCl (and complete dissociation of the NaCI salt), calculate the osmotic pressure of seawater at 25°C. (c) The average osmotic pressure of blood is 7.7 atm at 25°C. What concentration of glucose (C6H12O6) will be isotonic with blood? (d) Lysozyme is an enzyme that breaks bacterial cell walls. A solution containing 0.150 g of this enzyme in 210. mL of solution has an osmotic pressure of 0.953 torr at 25°C. What is the molar mass of lysozyme? (e) The osmotic pressure of an aqueous solution of a certain protein was measured in order to determine the protein's molar mass. The solution contained 3.50 mg of protein dissolved in sufficient water to form 5.00 mL of solution. The osmotic pressure of the solution at 25°C was found to be 1.54 torr. Calculate the molar mass of the protein.
A solution is made by dissolving 0.455 g of PbBr2 in 100 g of H2O at 50C. Based on the data in Table 8-1, should this solution be characterized as a. saturated or unsaturated b. dilute or concentrated

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(13) Calculate the freezing point of a solution containing 5.0 grams of KCl and 550.0 grams of water. The molal-freezing-point-depression constant (Kf) for water is 1.86°C/m. A) -0.45 OC B) +0.45 °C C) -0.23 OC D) +0.23 °C E) 1.23 oC