11. What alkenes would you start with to prepare the following products? (a) Br (a) (b) Vinylcyclohexane CH₂CH3 HBr 12. Show the structures of the carbocation intermediates you would expect the following reactions: CH3 CH3 CHCH3 HI ? CH3CH₂C=CHCHCH3 HBr ? (c) CH₂CH3 Br Br CH3CH₂CHCH₂CH₂CH3 (b) 13. On treatment with HBr, vinylcyclohexane undergoes addition and rearrangement to yield 1-bromo- 1-ethylcyclohexane. Using curved arrows, propose a mechanism to account for this result. (d) CI 1-Bromo-1-ethylcyclohexane
11. What alkenes would you start with to prepare the following products? (a) Br (a) (b) Vinylcyclohexane CH₂CH3 HBr 12. Show the structures of the carbocation intermediates you would expect the following reactions: CH3 CH3 CHCH3 HI ? CH3CH₂C=CHCHCH3 HBr ? (c) CH₂CH3 Br Br CH3CH₂CHCH₂CH₂CH3 (b) 13. On treatment with HBr, vinylcyclohexane undergoes addition and rearrangement to yield 1-bromo- 1-ethylcyclohexane. Using curved arrows, propose a mechanism to account for this result. (d) CI 1-Bromo-1-ethylcyclohexane
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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