11. BnoOACBF OEt,Gakurai RiwOBnCH,CN, rt- Crich's Cation clock-12.PベTE Oちつ、-。TfOBnO4n' MSS hint: becomesgood leaving grop13.:-NENetherring expancion product

Answered: Image /qna-images/answer/d2b5fd4d-fe29-4120-b948-71dbb1aa2be6.jpg

Answered: 11. Bn0 OAC BF OEt, Sakurai Riw OBn…

11. Bn0 OAC BF OEt, Sakurai Riw OBn CH,CN, rt - Crich's Cation clock- 0: a. PhT SMe, T0 CE, Bn O 4n MS TFO Phint: becomes good leaving grop 13. :C-NEN ether ring expansion product

Chemistry by OpenStax (2015-05-04)

1st Edition

ISBN:9781938168390

Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser

Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser

Chapter16: Thermodynamics

Section: Chapter Questions

Problem 2E: What is a nonspontaneous reaction?

See similar textbooks

Related questions

Q: 2.06 A KB/S O A R Question write the general reaction and mechanism of perkin reaction. Give 4…

A: The Perkin reaction is an organic reaction developed by English chemist William Henry Perkin that is…

Q: 10. NBS KOBr (A) . Product (A) is : LOH HO- NH (a) (b) (c) (d) -NH2 - NH2

A: This reaction is Hoffmann Bromamide name reaction and intermediate is 'nitrene'.

Q: Drawa mechanis m for this reaction, Dredictiny the Droduct -Be Sure to label eacharrcw withits…

A: Interpretation- To draw a mechanism for the given reaction which is given as -…

A: Methylene group: In organic compound Methylene group is a functional group and it has the chemical…

Q: What conditions give the transformation shown? H how? (1) Og: (2) ZnHOAC LI/ NH3lia) ob. (1) Brg:…

A: The given reaction is,

Q: oossible product of the reaction below сно OH H- H. CH,OH HO ??? H OH -OH ČH,OH

Q: Final step OEt HO HO. OH O. HN NH2 not formed in final step OEt 11 Target

A: An organic reaction in which the incoming nucleophile takes the position of a leaving group is…

Q: Drawa mechanis m for this reaction, Predic the Droduct tory -Be sue to label each anrcw with its…

Q: 1. HSCH,CH,CH,SH H BF3 OEt, 2. n-BuLi 3. Br 4. HgCl2 /H,O THF (solvent) 5. heat [3,3] sigmatropic…

A: It is an example of 1,3 dithiane reactionss. In this the aldehyde carbonyl group is…

Q: O fmd out the frost (M) tor the ow toansihon ometals forllowing Comyoun ds Cll them obey 18 e ete…

Q: Teken een geldige resona volgende bensielkation Draw one valid resonance intermediate for the…

A: Benzylic carbocation is stabilized through resonance.

Q: LAD LED LID LUD 15. the least stable carbocation 16. the most stabilized carbocation via…

Q: te a full mechanism for each reaction shown below. (I) Clearl (iii) show stereochemistry where…

A: According to our guideline, I can answer only the first three sub-parts.

Q: a) Find a single, simple (me othn funational graup) alkyl halide be readily conveitad into both of…

Q: What is/are the major product(s) of this reaction? HBr (R)-3-bromo-2,3-dimethylpentane only…

Q: Q1. Write down a detail step by step mechanism for the formation of 1-Bromobutane and 2-chloro-2-…

A: As per Markovnikov rule , the electron-rich component of the reagent adds to the carbon atom with…

Q: find the major products wode bas Isngia doso o NaOEt in qislum Jolduob Jols ELOH ol abnoqa - H3C H.…

Q: The Learning App Step -1 -Br - KBr" HO + K - 1/2 H, Step -2 H Он + K - 1/2 H, K* - KBr Ether…

Q: Consider the following alkyl halides: CI CI Br CI 1 HC C CH,CH, H-C -CH,CH,CH, HC-C-CH, HC-C-CH,CH3…

A: Please find below answers:

Q: Consider the free energy profile for the transformation A to G: C A What is the slowest step in the…

A: Answer: Whether step is slowest or fastest, that can be determine with the help of activation…

Q: 1. HSCH,CH,CH,SH H. BF3 OEt, 2. п-BuLi 3. Br 4. HgCl, /H,O THF (solvent) 5. heat [3,3] sigmatropic…

A: Step 1: Protecting the carbonyl group with the HSCH2CH2CH2SH in presence of BF3OEt2 as shown below.…

Q: Are all tnese rrachions stercoselective and how do you find it? 1) 1,3-dimethylcyclohex - 1-ene…

A: Here we have to identity whether the reactions are stereoselective or not. For stereo selective…

Q: 8. Hydroboration-oxidation leads to the syn addition of H and OH to a double bond. Before predicting…

A: “Hello. Since you have posted a question with multiple sub-parts, we will solve the first three…

Q: butan-1-ol butanal, CH3 CH2 CH2CHỎ. eq. NaOCI TEMPO 1 РСС NaOCI НОАС EtMgBr H;O+ H,CrO4 ether or PCC…

Q: 1,1-diphenylethanol after workup. 2 equiv. CH,CH, MgBr 1 equiv. CH, MgBr 1 equiv. PhMgBr 2 equiv.…

A: Since you have asked multiple question, we will solve the first question for you.If you want any…

Q: (Retro-Diels-Alder cycloadditions). example CN ČN CF3 MeO COME 14) Obtain the major product of [4+2]…

Q: sonance structures, starting materials, reagents, products, and any other mechanistic as pload your…

Q: Draw the energy verses course of rx curve (energy diagram) for the reaction 4 PH3 + 2 H2 + 9 02 5 2…

A: To draw the energy diagram , we would check what type of reaction is it . As reaction is at…

Q: j. SN1 SN2 E1 E2 H. H Br ČH3 - OH + Product(s)/Stereochemistry(ies) of reaction j_

A: Depending on the reaction condition and substrate used the product changes .

Q: 2 Conseeutive 3,3- sigmatropic rearrangements 2.

Q: Which conditions would achieve the following transformation? OCCH₂ ? --- a) CH,CI/AICI,, then…

Q: N02 Nitration conc. HNO3+ conc H2Sou Bentene NitHobenzene Mechanism:- Nittoanium ion NO2 + 0=N=0 →…

A: First reaction is the nitration of benzene. Nitration of benzene takes place in presence of…

Q: 1. -MgBr H3O*. H20, ether heat Step 1 product Step 2 product -CEN 2. H3O* · 1 product. Draw the step…

A: We will write the product of the given reaction

Q: Mostly Chapter 10, propose structures for A to K. КОН Na CH3CH2Br Br A C H2O ether ether Mg ether 1.…

A: We know that aq KoH will do substitution reaction with haloalkane. Na ,Mg are .metal which act like…

Q: Mostly Chapter 10, propose structures for A to F. CH3CH,Br B КОН Na Br А C H20 ether ether Mg ether…

Q: Tepkime: H(g) + BR,(g)--> HBr(g) + Br(g) O 1.13 kJ mol-1 O 7.19 J mol-1 O 7.19 kj mol-" -1.13 kJ…

A: For the reaction given below, the arrhenius actication energy is 15.5 kj.mol-1. Then Find Δ≠ H0

Q: Find the products (A and B) for the following reaction sequence: Br NaOEt, E1OH Brz, light B.

A: NaOEt act as a base and abstracts the proton results in the formation of alkene(A) by E2 mechanism.…

Q: #6 (a) How to add a amine functional group to a benzene ring?

A: Electrophilic aromatic substitution takes place when an electrophile displaces a hydrogen atom of an…

Q: NaBH4 OH OH LIAIH4 OH H. I OEt H. chemoselectivity How an do this reaction?

A: ->NaBH4 can not reduce ester group. ->LiAlH4 can reduce both ketone and ester into alcohol.

Q: what is the best mpound to make X o Give mechamism? compound OH (b) BY BY Br Nat

Q: Vhat is/are the missing reagent(s) "A" in the following reaction? HO ???? ОН NazCr204/H* O All of…

A: ->K2Cr2O7/H^+ and KMnO4 are strong reagent it oxidize alcohol to carboxylic acid.

Q: Projekt 4 HO OH = Mg Br/ => Proyett et is divedat in todays Dag one i prepar epory cybloerene od…

A: Synthesis : Reaction : cyclohexene reaction with mCPBA gives the epoxide. Reaction 2 : cyclohexene…

Q: Mostly Chapter 10, propose structures for A to K. CH3CH2BR В КОН Na Br A C H20 ether ether Mg ether…

Q: True or fasle? Conjugated carbonyls (with a double bond or benzene ring)will have increased…

A: Conjugated carbonyls will have increased stretches by 20-30 cm-1. Is this statement true or false?

Q: OCH3 OH CI O (2R,4Z)-4-chloro-2-hydroxy-5-methoxy-4-hepten-3-one O…

A: The rules for IUPAC naming is as follows 1. First we need to choose the longest carbon chain. 2.…

Q: 1. Provide the product of the reaction below. Show all stereochemistry NASCH, DMSO MacBook Pro

Q: H202 HQ write the mechanis af each reaction)

Q: What are the possible EAS products? X out any boxes that you do not use. осн Br-Br FeBr,

A: The possible EAS product can be drawn as

Q: (vi) Explain the differing reactivity in the two reactions below: H2/Pt Cd CO CH2 1 At., RT. Cal CO…

A: first reaction - H2/Pt means hydrogen electrode which has Platinum. Platinum metal is a catalyst…

Q: 1.0, PRODUCT I 2. Zn, H* MCPBA PRODUCT 2 cold dilute nuetral KMNO, PRODUCT 3 ool of Choices HO A в…

A: The question is based on the concept of organic reactions. We have to identify the product formed…

Concept explainers

Polymerization Kinetics

Polymerization is a chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that diverge in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes. Polymerization is generally classified into step-growth and chain polymerization. Polymers are categorized into linear polymer and cross-linked polymers that are produced either by condensation or additional polymerization.

Question

11. Bno
OAC
BF OEt,
Gakurai Riw
OBn
CH,CN, rt
- Crich's Cation clock-
12.
Pベ
TE O
ちつ、-。
TfO
BnO
4n' MS
S hint: becomes
good leaving grop
13.
:-NEN
ether
ring expancion product

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

12. Which one of the following is TRUE? Select one: O a AH°; for N (€) O b.AH, for Hg,* 2+ O CAH'dissociation for 0,(g) O dAHvag for Br (€) e. AH comb for CH, (g)
1. H2O; 2. KMnO4 1. O3; 2. DMS; 3. Na2Cr2O7/H2SO4/H2O 1. NaOH, Br2; 2. DMS; 3. H2O/heat 1. O3; 2. DMS; 3. KMnO4 1. DMS; 2. H2O/heat
Gven the reaction at 298K: 2 HyS Cg)t SOzlg) 35(5, rhombic) + 2H,0(g) a) Determine AH°rxn AH'oxn= Ky/mol %3D b) If AGn= -102 n7/mul,that is the change in eathaley Asan lin Jlmolk) 45oxn3= J/molK %3D pressule in atm of PH,s it AGrn i and PH,0 - 0. ol00 <)what is the -129 KJ, Psoz = 1.50 atm PHqS= %3D atm %3D
for the qaseous reaction of xenon & fluosine to foom Xenon :provided AH: - 4021J/mol & AG- -280-4 xehon Ę hexafluoride Imol 9) Colucu late As ct as°c b) find the equilibrium constant.
Given the data in the table below, AHrxn for the reaction Ca(OH); + 2H;AsO4 → Ca(H;AsO4)2 + 2H;O is _ kJ. [A] -4219 (B] -130.4 [C] -4519 [D] -76.4 AH, (kJ/mol) -986.6|| Substance Ca(ОН), HASO, Ca(H;AsOa)2 -900.4 -2346.0 H;0 -285.9 O A В C D
Use the values of AH to calulate AH for the follonng reactions. Substance and State AH (LJ/mol) Cag(PO,),(s) C&SO (s) CH,(G) HCN(9) HC(G) H,0(g) NH(9) NH,CI(s) 0,(0) HPO,(1) H,80,(1) 4126 -433 -75 135.1 -92 -242 -46 -314 -1267 -814 (2) + N OH 0O AH" b. Caa (PO), (s) + 31, SO.(1) + 3Ca$O.(s) + 2H,PO, (1) c NH3 (g) + HCIG) NH, CI(s) AH"= kJ 888
[Relerences Use the References to access important values if needed for this question. Complete the following operations by filling in the exponent for the result: = k (-)*- = a (-)(**)-a Veited Submit Answer Retry Entire Group No more group attempts remain
WHAT IS THE EQUIUBEUM CONSTANT EXPRESSION FOR THE FOUOWING REACTION ? SO3 cg) + Hz O (e) = E Hz SO4 (g)
Me 03, -78 °C then Zn, CH;CO2H
The dependence constant of the Of a reaction is ntcmparature given by the egoation_EaRT under what condition k the the smallest? as high I and Large Fa b.y hish I and smatt Eg low T and Lage Es and small
Reaction #1 Co() + 2H2(g) → CH:OH() AS° = -332 J/K CH.(g) + 0:(g) AS° = +162 J/K Reaction #2 CH:OH(!) – AH', AG; s° Substance (kJ mor) (kJ mot') (JK' mor') Co(g) -110.5 197.674 -238.7 -166.4 126.8 CH:OH(f) CH(g) -74.8 186.2 NOTE: You should be able to work this problem without using any additional tabulated data. (a) Calculate AH for reaction #1. (b) Calculate AGf for CO(g). (c) Calculate S° for O2(g). (d) At what temperatures is reaction #1 spontaneous?
Rank the metal ions by oxidizing strength and the metals by reducing strength from strongest to weakest Metal ions: Metals: Write balanced net equation for five of the combinations that produced reaction. And what are the reduction potential for the five combinations?