1. The following reaction (studied by Nakamura et al.) is performed by an alkylating enzyme called CylK: CylK но OH 2 alkylating enzyme но он но он The cytotoxic, cyanobacterial natural product formed is known as cylindrocyclophane F. Propose a mechanism for this step in its biosynthesis.

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter11: Ethers, Epoxides, And Sulfides
Section: Chapter Questions
Problem 11.37P: Following are the steps in the industrial synthesis of glycerin. Provide structures for all...
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1. The following reaction (studied by Nakamura et al.) is performed
by an alkylating enzyme called CylK:
CylK
но
OH
2
alkylating enzyme
но
он
но
он
The cytotoxic, cyanobacterial natural product formed is known as
cylindrocyclophane F. Propose a mechanism for this step in its
biosynthesis.
Transcribed Image Text:1. The following reaction (studied by Nakamura et al.) is performed by an alkylating enzyme called CylK: CylK но OH 2 alkylating enzyme но он но он The cytotoxic, cyanobacterial natural product formed is known as cylindrocyclophane F. Propose a mechanism for this step in its biosynthesis.
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