1. The first step in the production of nitric acid is the combustion of ammonia: 4NH, (g) + 50, (g) → 4NO (g) + 6H,0 (g) Write the equations that relate the rates of consumption of the reactants and the rates of formation of the products. 2. NO(g) + 0, (g) → NO, (g) + O; (g) This reaction has been studied in the laboratory, and the following rate data were determined at 25 °C Trial [NO] (mol/L) [0] (mol/L) AIN0 (molL-s Ar 1.00 x 10- 3.00 x 10-6 6.60 x 105 1.00 x 10-6 6.00 x 10-6 1.32 x 104 1.00 x 10- 9.00 x 10-6 1.98 x 104 4 2.00 x 10-6 9.00 x 10-6 3.96 x 104 3.00 x 10-6 9.00 x 10-0 5.94 x 104 Determine the rate law and the rate constant for the reaction at 25 °C. 2.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section11.7: Reaction Mechanisms
Problem 11.12E
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1. The first step in the production of nitric acid is the combustion of ammonia:
4NH, (g) + 50, (g) → 4NO (g) + 6H,0 (g)
Write the equations that relate the rates of consumption of the reactants and the rates of
formation of the products.
2.
NO(g) + 0, (g) → NO, (g) + O; (g)
This reaction has been studied in the laboratory, and the following rate data were
determined at 25 °C
Trial [NO] (mol/L)
[0] (mol/L) AIN0 (molL-s
Ar
1.00 x 10-
3.00 x 10-6
6.60 x 105
1.00 x 10-6
6.00 x 10-6
1.32 x 104
1.00 x 10-
9.00 x 10-6
1.98 x 104
4
2.00 x 10-6
9.00 x 10-6
3.96 x 104
3.00 x 10-6
9.00 x 10-0
5.94 x 104
Determine the rate law and the rate constant for the reaction at 25 °C.
2.
Transcribed Image Text:1. The first step in the production of nitric acid is the combustion of ammonia: 4NH, (g) + 50, (g) → 4NO (g) + 6H,0 (g) Write the equations that relate the rates of consumption of the reactants and the rates of formation of the products. 2. NO(g) + 0, (g) → NO, (g) + O; (g) This reaction has been studied in the laboratory, and the following rate data were determined at 25 °C Trial [NO] (mol/L) [0] (mol/L) AIN0 (molL-s Ar 1.00 x 10- 3.00 x 10-6 6.60 x 105 1.00 x 10-6 6.00 x 10-6 1.32 x 104 1.00 x 10- 9.00 x 10-6 1.98 x 104 4 2.00 x 10-6 9.00 x 10-6 3.96 x 104 3.00 x 10-6 9.00 x 10-0 5.94 x 104 Determine the rate law and the rate constant for the reaction at 25 °C. 2.
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