1. Mel (excess), THF 2. Ag20, H20 3. heat H2N Me 4. cat. Cp2La(NMe2) H,N Me

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Chapter1: Chemical Foundations
Section: Chapter Questions
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Predict the products and indicate the relative stereochemistry for the following transformations. When
necessary, indicate the major product.
1. Mel (excess), THE
2. Ag20, H20
3. heat
H2N Me
4. cat. Cp2La(NM@2)
H2N
Me
1. NaOMe, MEOH, heat
Me
Me Me
2. NaCN, DMF
3. NH4Cl(aq)
1. ΚΗ (2.05 equiv)
18-crown-6, THF
2.
Br-
Br
Me
OEt
3. H30*, heat
Transcribed Image Text:Predict the products and indicate the relative stereochemistry for the following transformations. When necessary, indicate the major product. 1. Mel (excess), THE 2. Ag20, H20 3. heat H2N Me 4. cat. Cp2La(NM@2) H2N Me 1. NaOMe, MEOH, heat Me Me Me 2. NaCN, DMF 3. NH4Cl(aq) 1. ΚΗ (2.05 equiv) 18-crown-6, THF 2. Br- Br Me OEt 3. H30*, heat
1. DIBAL-H, Et,O
2. H3O*, H2O
он ОМе О
HO.
OEt
Он ОМе
3. РTSOН, PhH, reflux
Ph
draw a-pyranose product
Transcribed Image Text:1. DIBAL-H, Et,O 2. H3O*, H2O он ОМе О HO. OEt Он ОМе 3. РTSOН, PhH, reflux Ph draw a-pyranose product
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