1. Complete the road map by providing the structures of the products as needed in the boxesprovided below. Please note, there may be more than one reagent needed for some of thesteps.1. NaOEV/EtOHOEt 2. dil. H+сныLDANaOEV/EtOHCH3CH2CH2CH₂BrΚΗ-78°CCH3CH2CH2CH2BrH₂O, H₂O", heat

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Answered: 1. Complete the road map by providing…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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#16c. Provide the missing reactants, reagents, or products for the following reaction sequences below.
Give the major organic product of the following reaction. 1) ВН3/THF 2) NaOH, H2O2 HO OH HO- OH There is no reaction under these conditions or the correct product is not listed here.
2. Complete the road map by providing the structures of the products or the reagents as needed in the boxes provided below. Please note, there may be more than one reagent needed for some of the steps. H HSCH2CH2CH2SH AICI 3 or H3O+ Δ BuLi 1. 요 2. H3O+ H2CrO3 HgO, H₂O, H+
Provide the reagents necessary to carry out the following conversion: 4-methyl-cyclohexanol -------> 4-methyl- cyclohexanone O KMNO4/NAOH/H20 peroxyacetic acid O Br2, CCl, O NazCr207/H2SO2/H2O O OsO4
Complete the reaction scheme below. Show all reagents and intermediates. No reaction is a possible answer. 1) CH3CH2M9B CH3OH H+ (ехcess) но 2) H30*, H2O B A OCH3
2. Complete the road map by providing the structures of the products or the reagents as needed in the boxes provided below. Please note, there may be more than one reagent needed for some of the steps. H HSCH2CH2CH2SH AICI 3 or BuLi 1. 요 2. H3O+ H3O+ H2CrO3 HgO, H₂O, H+
1. Br₂, PBrg 2. H₂O H₂C OH H3C OH Br The a-bromination of carbonyl compounds by Br₂ in acetic acid is limited to aldehydes and ketones because acids, esters, and amides don't enolize to a sufficient extent. Carboxylic acids, however, can be a-brominated by first converting the carboxylic acid to an acid bromide by treatment with PBr3. Following enolization of the acid bromide, Br₂ reacts in an α- substitution reaction. Hydrolysis of the acid bromide completes the reaction. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions H3C :0: :0::Br: Br Br H3C CO-P H Br Br
Provide the necessary reagents to accomplish the desired organic reactions. Please number the steps and note that some reactions will require more than one step. Me Meo. Meo. CF MeO
1.When 2-methyl-1-butanol is dehydrated in an acid medi- um to an alkene, it yelds mainly 2-methyl-2-butene rather than 2-methyl-1-butene. This indicates that the dehydra- tion to an alkene is at least a two-step reaction. Suggest a mechanism to explain the reaction.
Which of the following structures and IUPAC names are incorrectly matched? * oe (A) Methyleyclohexanoate (В) `NH2 Br 4-Bromo-3-chlorohexanamide 2-Ethoxypentane (D) HOOC HOOC 3,5-Nonanedioic acid В A D
4. Aldehydes and ketones can be “protected" as acetals and ketals. Complete the following outlined reactions, showing how the protection is accomplished, and what results after deprotection. MgCI 1) 2) HO* deprotection here
What, in general, is the order of decreasing reactivity of these carbonyl compounds towards nucleophilic reagents? H H CH3CCH3 CH3C=0 (CH 3)3CCCH3 HC=0 (CH3)3CCC(CH 3)3 I II III IV V O I> III > IV> I > V O v> III >I> I| > IV O I> IV > || > II > V O IV > || >1>III > V

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