1) Prepare a molecular orbital energy-level diagram for BrO [sp mixing is not significant in BrO] Orbital potential energies: Br: 4s -24.37 eV, 4p -12.49 eV; O: 2s -32.38 eV, 2p: -15.85 eV 2) Sketch the molecular orbital pictures (schematic representations) for the HOMO and LUMO in your MO diagram. 3) Hypobromite (BrO) is the bromine compound analogous to hypochlorites found in common bleaches, and in immune cells. In many ways, hypobromite functions in the same manner as hypochlorite, and is also used as a germicide and antiparasitic in both industrial applications, and in the immune system. For example, BrO can oxidize sulfhydryl groups in proteins. Which molecular orbital(s) of BrO would you predict to interact most strongly with the sulfhydryl groups in the protein to oxidize them? Explain.
1) Prepare a molecular orbital energy-level diagram for BrO [sp mixing is not significant in BrO] Orbital potential energies: Br: 4s -24.37 eV, 4p -12.49 eV; O: 2s -32.38 eV, 2p: -15.85 eV 2) Sketch the molecular orbital pictures (schematic representations) for the HOMO and LUMO in your MO diagram. 3) Hypobromite (BrO) is the bromine compound analogous to hypochlorites found in common bleaches, and in immune cells. In many ways, hypobromite functions in the same manner as hypochlorite, and is also used as a germicide and antiparasitic in both industrial applications, and in the immune system. For example, BrO can oxidize sulfhydryl groups in proteins. Which molecular orbital(s) of BrO would you predict to interact most strongly with the sulfhydryl groups in the protein to oxidize them? Explain.
Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter10: Molecular Structure And Bonding Theories
Section: Chapter Questions
Problem 10.116QE
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