. Give the chemical formula that corresponds to each of the following compounds:(a) Sodium tetrahydroxozincate(II)(b) Dichlorobis(ethylenediamine)cobalt(III) nitrate(c) Triaquabromoplatinum(II) chloride(d) Tetra-amminedinitroplatinum(IV) bromide

. Give the chemical formula that corresponds to each of the following compounds:(a) Sodium tetrahydroxozincate(II)(b) Dichlorobis(ethylenediamine)cobalt(III) nitrate(c) Triaquabromoplatinum(II) chloride(d) Tetra-amminedinitroplatinum(IV) bromide

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes

Section: Chapter Questions

Problem 73AP

See similar textbooks

Related questions

Q: Explain in words how potassium aluminum sulfate is formed via ligand exchange. Indicate clearly the…

A: A ligand exchange reaction is a reaction which involves the substitution of one or more ligands in a…

Q: Explain the differences between weak-field and strong-field metal complexes?

A: Differences between weak-field and strong-field metal complexes:

Q: Ligand A, B, and C form complexes with a metal cation resulting to violet, indigo, and blue aqueous…

Q: How many different formulas are there for octahedral complexes with a metal M and four ligands A, B,…

A: The complexes in which the central metal atom is surrounded by six ligands are called an octahedral…

Q: By plotting the structure of the dinitro tetraammin cobalt (III) chloride complex compound, specify…

A: Any compound that is written within square brackets is called a coordination compound. The ions…

Q: Hexaamminechromium(III) ion, [Cr(NH3)6]°* is a metal complex containing six ammonia ligands i. Using…

Q: Explain the ways in which the elements act: (a) How do you explain that fluoride, a small anion, is…

A: Explanation for the given parts a and b.

Q: The complex potassium dicyanoargenate(I) is used to make antiseptic compounds. Give the formula and…

Q: The octahedral ion complex [CoF6] 3‒ absorbs at 675 nm. (a) What color is the complex? (b)…

Q: Describe the types of NO bonds by demonstrating the electrons involved. This is an acid (pi) ligand…

A: The metal uses t2g orbital to form pi bonds with ligands. Pi star orbital of metal is high energy…

Q: Which of the actinides are radioactive?

A: In a periodic table, element having atomic number from 89 to 103 are termed as actinides. Therefore,…

Q: Consider the compound (C8H8)Ru(CO)3 which is likely to be the best description of the C8H8 ligand ?

A: The stability of any organometallic compound is given by Effective Atomic Number (EAN Rule).…

Q: Write the formula for each of the following compounds, being sure to use brackets to indicate the…

A: The Formula for the following coordination compounds are: (a)…

Q: Hexaamminechromium(III) ion, [Cr(NH3)s]³* is a metal complex containing six ammonia ligands i. Using…

A: A question based on coordination compounds that is to be accomplished.

Q: Draw the structures and give the stock names of complexes that can satisfy the conditon: 1.…

A: The given condition is: Geometric isomers of anionic complexes containing hexacoordinated Os4+ and…

Q: 3+ (d) [Cr(OH)2]6* ions are pale blue-green but chromate (Cr,O,) ion is an intense yellow in colour.…

Q: (a) [Cr(II)(H2O)6]2+ and [Cr(III)(H2O)6]3+ display markedly different ligand exchange rates. Which…

A: Introduction : We have to study about ligand for these type of questions .

Q: Write the formula for each of the following compounds, being sure to use brackets to indicate the…

A: Rules for writing the formula of the complex: Write the chemical symbol of the central atom…

Q: ron(III) chloride reacts with triphenylphosphine,PPh3, to form the complex [FeCl3(PPh3)2]. However,…

Q: Plot the structure of the dinitro tetraammine cobalt (III) chloride complex compound and indicate…

A: Given, Complex compound is dinitro tetraammine cobalt(III) chloride, In this complex compound,…

Q: The complexes [V(H2O)6]3+ and [VF6]3- are both known.(a) Draw the d-orbital energy-level diagram for…

A: SOLUTION: Step 1: a. The orbital energy level diagram for V(III) octahedral complex is as follows:

Q: Write the formula for each of the following compounds, being sure to use brackets to indicate the…

A: In chemistry, the molecular formula represents the compound that is denoted by the element's symbol…

Q: Estimate the wavelength of maximum absorption for the octahedral ion hexacyanoferrate(III) from the…

A: Given that the light which is emitted by the solution is red, hence the solution absorbs its…

Q: How does Ligand Field Theory explain the interaction between the ligand with the central metal…

A: Crystal Field theory explains bonding for transition metal complexes. The energy of crystal field…

Q: Explain giving reasons :(i) Transition metals and their compounds generally exhibit a paramagnetic…

A: Transition elements are the elements having partially filled d-subshell and the elements of this…

Q: Explain why, for the same metallic cation and the same ligands, the energy of the binding field is…

A: The question is based on the concept of coordination chemistry. We have to explain the low binding…

Q: Explain the hybrid type and geometric structure of the K3 [Cr (C204) 3] .3H2O complex with VBT.

A: oxidation number of Cr is +3 in this compound .

Q: Pyridine (C5H5N), abbreviated py, Would you expect pyridine to act as a monodentate or bidentate…

A: Ligands are electron rich species. The electrons are donated to the central metal atom. The given…

Q: Giving one example in each of the following cases, discuss briefly the role of coordination…

A: Introduction- Coordination compounds- These are the compounds which contain a complex part formed…

Q: When cobalt (II) chloride is treated, under certain conditions, with the bidentate ligand,…

A: i) Let the oxidation state of Co be x, the bidentate ligand, NH2CH2CH2NH2, is a neutral species so…

Q: Which atom is a common linkage site in polydentate ligands?

A: Polydendate ligands are those ligands which have more than 2 donar atoms .

Q: Will methylamine (CH3NH2) be a monodentate or abidentate ligand? With which of its atoms will it…

A: Will methylamine (CH3NH2) be a monodentate or a bidentate ligand? With which of its atoms will it…

Q: What are the characters for the operations C2, C4, σd, and σv(xz) respectively, on the LCAO Ψ(L1+L3)…

A: Cn is a rotation of (360/n)". C2= 180°rotation, C4= 90°rotation

Q: In what directions do you expect the bond length andvibrational frequency of a free CO molecule to…

A: Interpretation - In what directions the bond length and vibrational frequency of a free CO molecule…

Q: y8gngu. Amino acids can act as ligands toward transition metal ions. The simplest amino acid is…

A: Ligands are the electron donating neutral or anionic group that donates the atleast one electron…

Q: A coordination compound has the following composition (by mass %): 23.53% Co; 42.47% Cl, and 34.00%…

Q: Describe how magnetism in lanthanides series arises

A: Instead making this explanation complex let me explain you in very simple language. As we know that…

Q: What is required of Lewis bases to act as ligands in coordination compounds?

A: Lewis base is a species which can donate electron pair to a Lewis acid.

Q: Write the examples of Bidentate and Polydentate ligands? Also distinguish them.

A: Ligands can be described as an anions or cations or neutral molecules which is further classified as…

Q: Are bipyridines (bipy) and analogous amines, phenanthroline (phen) and terpyridine (terpy) chelate…

A: Yes, bipyridine and analogous amines, phenanthroline and terpyridine are chelate ligands.

Q: For the following coordination complex: :{Zn(NH3)2C12} Give the name Determine the geometry Give the…

A: For the IUPAC name, first we find the oxidation no. Oxidation no. of Zn = 2 The IUPAC name is =…

Q: Describe the periodic trends in radii and oxidation states of the transition-metal ions, including…

A: Lanthanide contraction occurs due to an increase in the effective nuclear charge with an increasing…

Q: Write the formula for each of the following compounds, being sure to use brackets to indicate the…

A: Given compounds, (a) tetraaquadibromomanganese(III) perchlorate (b) bis(bipyridyl)cadmium(II)…

Concept explainers

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.

Question

. Give the chemical formula that corresponds to each of the
following compounds:
(a) Sodium tetrahydroxozincate(II)
(b) Dichlorobis(ethylenediamine)cobalt(III) nitrate
(c) Triaquabromoplatinum(II) chloride
(d) Tetra-amminedinitroplatinum(IV) bromide

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

Step 2

Step 3

Step 4

Trending now

This is a popular solution!

Step by step

Solved in 4 steps with 4 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Predict the products of each of the following reactions and then balance the chemical equations.(a) Fe is heated in an atmosphere of steam.(b) NaOH is added to a solution of Fe(NO3)3.(c) FeSO4 is added to an acidic solution of KMnO4.(d) Fe is added to a dilute solution of H2SO4.(e) A solution of Fe(NO3)2 and HNO3 is allowed to stand in air.(f) FeCO3 is added to a solution of HClO4.(g) Fe is heated in air.
Name the compounds (a) [Mo(NH3)3Br3]NO3,(b) (NH4)2[CuBr4]. (c) Write the formula for sodium diaquabis(oxalato)ruthenate(III).
Give the oxidation state of the metal for each of the following oxides of the first transition series. (Hint: Oxides of formula M3O4 are examples of mixed valence compounds in which the metal ion is present in more than oneoxidation state. It is possible to write these compound formulas in the equivalent format MO∙M2O3, to permit estimation of the metal’s two oxidation states.)(a) Sc2O3(b) TiO2(c) V2O5(d) CrO3(e) MnO2(f) Fe3O4(g) Co3O4(h) NiO(i) Cu2O
Describe/draw the formation of bond in the following compounds: (i) CaCl2 (ii) K2O (iii) O2
Explain the ways in which the elements act: (a) How do you explain that fluoride, a small anion, is responsible for a weak field while water, a neutral molecule, gives rise to a much stronger binding field? (b) Explain why, for the same metallic cation and the same ligands, the energy of the binding field is lower in tetrahedral compounds than in octahedral compounds.
(b) Consider the oxalate (ox) ligand and answer the following questions:(i) Draw the structure of the ox ligand.(ii) Identify all the donor atoms of the ligand.(iii) What is the denticity of the ligand?(iv) What is the charge of the ligand?(v) Draw the structure of a homoleptic octahedral complex with ox as the ligand.Clearly show the geometry at the metal centre.(vi) Identify the stereoisomer in the structure drawn.
Using IUPAC norms write the formulae for the following:(a) Tris(ethane-1,2-diamine) chromium (III) chloride(b) Potassium tetrahydroxozincate(II)
Trimethylphosphine, P(CH3)3, can act as a ligand by donating the lone pair of electrons on the phosphorus atom. If trimethylphosphine is added to a solution of nickel(II) chloride in acetone, a blue compound that has amolecular mass of approximately 270 g and contains 21.5% Ni, 26.0% Cl, and 52.5% P(CH3)3 can be isolated. This blue compound does not have any isomeric forms. What are the geometry and molecular formula of the bluecompound?
(a) An aqueous solution of Fe(NO3)3 has only a pale color, but an aqueous solution of K3[Fe(CN)6] is bright red. Do you expect a solution of K3[FeF6] to be brightly colored or pale? Explain your reasoning.(b) Would you predict a solution of K2[HgI4] to be colored or colorless? Explain.
Write the formula for each of the following compounds, being sure to use brackets to indicate the coordination sphere: (a) tetraaquadibromomanganese(III) perchlorate (b) bis(bipyridyl)cadmium(II) chloride
(a) Give the chemical name of Ir(CO)CI(PPh 3 ) 2 (either of the two isomers). (b) Sketch all isomers of the octahedral complex Cr(H2O), FBrCl (hint: there are five, and two of the five are enantiomers of each other).
Write the formula for sodium diaqua-bis(oxalato)ruthenate(III).