The following endothermic reaction is found to be at equilibrium at room temperature. NH4HS(s) ⇌ NH3(g) + H2S(g) Comment on the changes in reaction composition (products and reactants) expected to arise under the following circumstances. (a)  The addition of NH3. (b)  An increase in pressure (at constant temperature) by decreasing the container volume (c)  An increase in pressure by the addition of an inert gas.

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Chapter13: Chemical Equilibrium
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Problem 13Q: Suppose a reaction has the equilibrium constant K = 1.3 108. What does the magnitude of this...
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1. The following endothermic reaction is found to be at equilibrium at room temperature.

NH4HS(s) ⇌ NH3(g) + H2S(g)


Comment on the changes in reaction composition (products and reactants) expected to arise under the following circumstances.

(a)  The addition of NH3.

(b)  An increase in pressure (at constant temperature) by decreasing the container volume

(c)  An increase in pressure by the addition of an inert gas.

(d)  An increase in temperature (justify using the appropriate thermodynamic expression).

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