Estimate the enhancement of the mass transfer rate for SO2 absorption. For SO2, the pertinent reactions are SO₂(g)+H₂O H₂SO, H₂SO, 2 HSO, +H* HSO, SO₂+H* At neutral pH, H2SO3 rapidly dissociates, and the SO2 reaction with water becomes pseudo-first order, given as SO₂- products For SO₂, the rapid hydrolysis reaction dramatically enhances the rate of absorption. The first-order rate constant ki at 20°C is 3.4 x 106 s-1

Introduction to Chemical Engineering Thermodynamics
8th Edition
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Chapter1: Introduction
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Estimate the enhancement of the mass transfer rate for SO2 absorption. For SO2, the
pertinent reactions are
SO₂(g)+H₂O H₂SO,
H₂SO,
HSO, +H*
HSO, SO, +H*
At neutral pH, H2SO3 rapidly dissociates, and the SO2 reaction with water becomes
pseudo-first order, given as
SO₂- products
For SO2, the rapid hydrolysis reaction dramatically enhances the rate of absorption. The
first-order rate constant k₁ at 20°C is 3.4 x 106 s-1
Transcribed Image Text:Estimate the enhancement of the mass transfer rate for SO2 absorption. For SO2, the pertinent reactions are SO₂(g)+H₂O H₂SO, H₂SO, HSO, +H* HSO, SO, +H* At neutral pH, H2SO3 rapidly dissociates, and the SO2 reaction with water becomes pseudo-first order, given as SO₂- products For SO2, the rapid hydrolysis reaction dramatically enhances the rate of absorption. The first-order rate constant k₁ at 20°C is 3.4 x 106 s-1
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