Compounds might have more than pKa.

Chemistry: An Atoms First Approach
2nd Edition
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Steven S. Zumdahl, Susan A. Zumdahl
Chapter14: Acid- Base Equilibria
Section: Chapter Questions
Problem 4RQ: A good buffer generally contains relatively equal concentrations of weak acid and conjugate base. If...
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4. Compounds might have more than pKa. 

5. We usually prefer to prepare buffers from alkaline origin compounds. 

6. The pH of a buffer solution containing .1 M acetic acid and 0.1 M sodium acetate? (Ka for acetic acid = 1.75 ×10-5) is 3.9. 

7. The pH of a solution containing ephedrine 0.1 M and ephedrine HCI 0.01 M? (Kb for ephedrine = 2.3 x 10-5) is 7.99. 

8. The maximum buffer capacity for solutions can be achieved when the required pH double than pKa of the acid.. 

9. When one of the buffer components is depleted completely the solution lose its buffering capacity and can no longer resist the change in pH. 

10. At a hydrogen ion concentration of 1.75 x 10-5, what is the capacity of a buffer containing 0.10 mole each of acetic acid and sodium acetate per liter of solution? (Ka = 1.75 x 10-5 ) is 9.11.

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