Black smokers are found in the depths of the oceans. Thinking that the conditions in these smokers might be conducive to the formation of organic compounds, two chemists in Germany found the following reaction could occur in similar conditions. 2 CH3SH+CO→ CH3COSCH3 + H₂S If you begin with 11.8 g of CH3SH and excess CO, what is the theoretical yield of CH3COSCH 3? 9 CH, COSCH, If you isolate 8.03 g of CH3COSCH3, what is the percent yield of CH3COSCH 3¹? %

Black smokers are found in the depths of the oceans. Thinking that the conditions in these smokers might be conducive to the formation of organic compounds, two chemists in Germany found the following reaction could occur in similar conditions. 2 CH3SH+CO→ CH3COSCH3 + H₂S If you begin with 11.8 g of CH3SH and excess CO, what is the theoretical yield of CH3COSCH 3? 9 CH, COSCH, If you isolate 8.03 g of CH3COSCH3, what is the percent yield of CH3COSCH 3¹? %

Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter4: Stoichiometry

Section: Chapter Questions

Problem 4.87PAE

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4.8 In an experiment carried out at very low pressure, 13x1015 molecules of H2 are reacted with acetylene, C2H2, to form ethane, C2H6, on the surface of a catalyst. Write a balanced chemical equation for this reaction. How many molecules of acetylene are consumed?
Ethanol, C2H5OH, is a gasoline additive that can be produced by fermentation of glucose. C6H12O62C2H5OH+2CO2 (a) Calculate the mass (g) of ethanol produced by the fermentation of 1.000 lb glucose. (b) Gasohol is a mixture of 10.00 mL ethanol per 90.00 mL gasoline. Calculate the mass (in g) of glucose required to produce the ethanol in 1.00 gal gasohol. Density of ethanol = 0.785 g/mL. (c) By 2022, the U. S. Energy Independence and Security Act calls for annual production of 3.6 1010 gal of ethanol, no more than 40% of it produced by fermentation of corn. Fermentation of 1 ton (2.2 103 lb) of corn yields approximately 106 gal of ethanol. The average corn yield in the United States is about 2.1 105 lb per 1.0 105 m2. Calculate the acreage (in m2) required to raise corn solely for ethanol production in 2022 in the United States.
Acetone, (CH3)2CO, is an important industrial compound. Although its toxicity is relatively low, workers using it must be careful to avoid flames and sparks because this compound burns readily in air. Write the balanced equation for the combustion of acetone.
The pictures below show a molecular-scale view of a chemical reaction between H2 and CO to produce methanol, CH3OH The box on the left represents the reactants at the instant of mixing, and the box on the right shows what is left once the reaction has gone to completion. D Was there a limiting reactant in this reaction? If so, what was it? Write a balanced chemical equation for this reaction. As usual, your equation should use the smallest possible whole number coefficients for all substances.
Write the balanced chemical equation for the complete combustion of adipic acid, an organic acid containing 49.31% C, 6.90% H, and the remainder O, by mass.
3.14 A number of compounds are used in cement, and reactions among them occur when water is added. In one, CaO reacts with Al2O3 and water to form Ca3Al2(OH)12. Write a bal- anced chemical equation for this process.
3.92 Many chemical reactions take place in the catalytic con- verter of a car. In one of these reactions, nitric oxide (NO) reacts with ammonia (NH3) to give nitrogen (N2) and water. Write a balanced equation for this reaction.
3.90 Pyrrole has the molecular formula C4H5N. When pyrrole reacts with O2, the products are CO2, H2O, and N2. Write a balanced equation for this reaction.
4.21 Ammonium nitrate, NH4NO3, will decompose explosively to form N2, O2, and H2O, a fact that has been exploited in terrorist bombings. What mass of nitrogen is formed by the decomposition of 2.6 kg of ammonium nitrate?
A 0.20 mol sample of magnesium burns in air to form 0.20 mol of solid MgO. What amount (moles) of oxygen (O2) is required for a complete reaction?
High cost and limited availability of a reactant often dictate which reactant is limiting in a particular process. Identify the limiting reactant when the reactions below are run, and come up with a reason to support your decision. a. Burning charcoal on a grill: C(s)+O2(g)CO2(g) b. Burning a chunk of Mg in water: Mg(s)+2H2O(l)Mg(OH)2(aq)+H2(g) c. The Haber process of ammonia production: 3H2(g)+N2(g)2NH3(g)

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