2) Complete the following: Stereochemistry and regiochemistry may be important. (10 pts) a) MeO₂C b) c) d) e) type type type type type NH, a) b) CO₂Et a) b) MeO₂C a) b) c) Acetoacetic ester synthesis a) NaH, THF b) BnBr, THF c) aq, NaOH; aq. HCI; D Aldol Condensation IZ CO₂Et CO₂Et O CO₂H CHO f) g) h) i) j) type type type O type H type a) CO,Et b) c) tor Br CO₂H Selective Catalytic Hydrogenation -Não ol EtOH OEt O a) SOCI2, D b) p-MeC6H4OH AICI3, C6H5NO2₂ OH HO H
2) Complete the following: Stereochemistry and regiochemistry may be important. (10 pts) a) MeO₂C b) c) d) e) type type type type type NH, a) b) CO₂Et a) b) MeO₂C a) b) c) Acetoacetic ester synthesis a) NaH, THF b) BnBr, THF c) aq, NaOH; aq. HCI; D Aldol Condensation IZ CO₂Et CO₂Et O CO₂H CHO f) g) h) i) j) type type type O type H type a) CO,Et b) c) tor Br CO₂H Selective Catalytic Hydrogenation -Não ol EtOH OEt O a) SOCI2, D b) p-MeC6H4OH AICI3, C6H5NO2₂ OH HO H
Chapter23: Carbonyl Condensation Reactions
Section23.SE: Something Extra
Problem 35MP: Isoleucine, another of the twenty amino acids found in proteins, is metabolized by a pathway that...
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Transcribed Image Text:2) Complete the following: Stereochemistry and regiochemistry may be important. (10 pts)
a)
MeO₂C
b)
c)
d)
e)
type
type
type
type
type
NH, a)
b)
CO₂Et
a)
b)
MeO₂C
a)
b)
c)
Acetoacetic ester synthesis
a) NaH, THF
b) BnBr, THF
c) aq, NaOH; aq. HCI; D
Aldol Condensation
IZ
CO₂Et
CO₂Et
O
CO₂H
CHO
f)
g)
h)
i)
j)
type
type
type
O
type
H
type
a)
CO,Et b)
c)
tor
Br
CO₂H
Selective Catalytic Hydrogenation
-Não
ol
EtOH
OEt
O
a) SOCI2, D
b) p-MeC6H4OH
AICI3, C6H5NO2₂
OH
HO H
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